Interactions | Reactions | Processes
Warning: Undefined variable $contentTYPE in /home/www/chemthes/rxn.php on line 104
Classified as: Radical Cleavage
Warning: Undefined variable $contentTEXT in /home/www/chemthes/rxn.php on line 234
Radical cleavage (also called radical fragmentation or homolytic fission) occurs when a chemical bond undergoes homolytic fission to yield a pair of radicals.
For more information look in the Chemogenesis webbook sections on fragmentation reactions and dealing with radical chemistry.
(C6H5COO)2 |
+ |
hν |
 |
|
|
 |
+ |
|
|
|
|
|
Cl2 |
+ |
hν |
|
|
|
2 |
Cl• |
|
|
|
|
|
Br2 |
+ |
hν |
|
|
|
Br• |
+ |
Br• |
|
|
|
|
 |
|
|
|
|
 |
+ |
CH3• |
|
|
|
|
|
|
|
|
|
CH3• |
+ |
CO |
|
|
|
|
 |
+ |
hν |
|
|
|
|
+ |
CH3CH2• |
|
|
|
|
 |
+ |
hν |
|
|
|
|
+ |
(CH3)3C• |
|
|
|
|
[H2O2]+• |
|
|
|
|
HO• |
+ |
[OH]– |
|
|
|
|
(CH3CO)2CO |
|
|
|
|
H2C=C=O |
+ |
CH3COOH |
|
|
|
|
|
+ |
hν |
|
|
|
|
+ |
CH3• |
|
|
|
|
2 |
H• |
|
|
|
|
H2 |
|
|
|
|
|
 |
+ |
m |
|
|
|
CO |
+ |
H• |
+ |
m* |
|
|
|
CH4 |
+ |
m* |
|
|
|
CH3• |
+ |
H• |
+ |
m |
|
|
|
 |
+ |
O2 |
|
|
|
CO |
+ |
HO• |
|
|
|
|
 |
+ |
3 |
O2 |
+ |
CH3COOH |
|
|
 |
+ |
2 |
H2O |
|
|
|
|
 |
|
|
|
|
 |
+ |
 |
|
|
|
|
 |
|
|
|
|
|
+ |
CH3–CH=CH2 |
|
|
|
|
 |
|
|
|
|
 |
+ |
3 |
H2C=CH2 |
+ |
2 |
CH3–CH=CH2 |
|
|
|
© Mark R. Leach 1999 –
Queries, Suggestions, Bugs, Errors, Typos...
If you have any:
Queries
Comments
Suggestions
Suggestions for links
Bug, typo or grammatical error reports about this page,please contact Mark R. Leach, the author, using mark@meta-synthesis.com