Interactions | Reactions | Processes


Classified as: Elimination

Elimination involves an electrofuge and a nucleofuge, or a pair of radicals, leaving an organic moiety to form a pi-system.

For more information look in the Chemogenesis webbook sections on fragmentation reactions and elimination reactions.


  +  
H2SO4
         
CH3–CH=CH2
  +  
H2O
  +  
H2SO4

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RCHO
  +  
         

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R–NH2
  +  
10
CH3I
  +  
Ag2O
         
  +  
(CH3)3N

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  +  
Base
Proton abstractor
         
  +  
Cl

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  +  
Base
Proton abstractor
         
  +  
Br

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  +  
Base
Proton abstractor
         
  +  
HI

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  +  
         
  +  
(C6H5)3P=O

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  +  
Pt
         
  +  
3
H2

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R–C–R
  +  
  +  

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  +  
  +  

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  +  
  +  

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  +  
  +  

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  +  
[OH]
         
  +  
(CH3)3N
  +  
H2O

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(CH3)3CBr
         
  +  
HBr

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  +  
(CH3)3N
         
  +  
[CN]
  +  
[(CH3)3NH]+

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H2C=CH2
  +  
RCOOH

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(CH3)2CHBr
  +  
CH3CH2O
  +  
CH3CH2OH
         
CH3–CH=CH2
  +  
  +  
Br
  +  
CH3CH2OH

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  +  
[OH]
         
  +  
(CH3)3N
  +  
H2O

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CH2ClCH2Cl
  +  
CH3CH2O
         
H2C=CHCl
  +  
Cl
  +  
CH3CH2OH

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(CH3)2CHBr
  +  
CH3CH2O
         
CH3–CH=CH2
  +  
Br
  +  
CH3CH2OH

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  +  
CO2
  +  
CO

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  +  
Aconitase
         
  +  
H2O

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  +  
Isocitrate
Dehydrogenase
         
  +  
CO2

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HCOOH
  +  
H2SO4
         
CO
  +  
H2O

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CH3CH2OH
  +  
H2SO4
         
H2C=CH2
  +  
H2O

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  +  
FeO.Fe2O3
         
  +  
H2

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  +  
Al2O3
         
  +  
H2

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CHCl3
  +  
NaOH
         
CCl2
  +  
NaCl
  +  
H2O

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CHCl3
  +  
Base
Proton abstractor
         
CCl2
  +  
Base-H
Protonated base
  +  
Na+

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CH2ClCH2Cl
         
H2C=CHCl
  +  
HCl

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  +  
HBr

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  +  
Pt
         
  +  
4
H2

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(CH3)3COH
         
  +  
H2O

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  +  
CH3OH
  +  
H2SO4
  +  
H2O
         
  +  
[NH4]+
  +  
[HSO4]
  +  
H2O

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  +  
H2

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CH3OH
  +  
Ag
         
HCHO
  +  
H2

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  +  
H2C=CH2

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  +  
CH3–CH=CH2

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Naphtha
         
Gasoline
  +  
H2C=CH2
  +  
CH3–CH=CH2

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Gas Oil
         
Gasoline
  +  
H2C=CH2
  +  
CH3–CH=CH2

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Naphtha
  +  
Gas Oil
         
  +  
  +  
  +  

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Naphtha
  +  
Gas Oil
         
  +  
  +  

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Naphtha
  +  
Gas Oil
         
  +  

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  +  
2
H2O

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2
CH3CHO
         

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  +  
  +  
  +  
         
  +  
H2

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  +  
ZnO
         
  +  
H2

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CH3CHCl2
  +  
Cl2
  +  
SiO2
         
CH3CCl3
  +  
HCl

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H2C=CHCl
  +  
HF
         
  +  
HCl

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CH2ClCH2Cl
  +  
3
Cl2
         
Cl2C=CCl2
  +  
4
HCl

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  +  
H+
         
  +  
H2O

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CH3CHO
  +  
HCHO
  +  
SiO2
         
  +  
H2O

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  +  
H3PO4
  +  
Cu
         

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  +  
CH3OH
  +  
H3PO4
  +  
Cu
         
  +  
H2O

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  +  
Al2O3
         
  +  
H2O

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  +  
HBr

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  +  
KOH
  +  
CH3CH2OH
         
  +  
KBr
  +  
H2O

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  +  
NaOH
  +  
CH3CH2OH
         
  +  
NaBr
  +  
H2O

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2
  +  
2
KOH
  +  
CH3CH2OH
         
  +  
  +  
2
KBr
  +  
2
H2O

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2
  +  
H2SO4
         
  +  

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(CH3)2CHBr
  +  
KOH
  +  
CH3CH2OH
         
CH3–CH=CH2
  +  
KBr
  +  
H2O

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3
  +  
3
KOH
  +  
CH3CH2OH
         
  +  
  +  
  +  
3
KBr

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H2C=CH2
  +  
H2O
  +  
H+

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2
  +  
2
NaOH
         
  +  
CH3–CH=CH2
  +  
2
NaCl
  +  
H2O

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2
(CH3)2CHBr
  +  
2
KOH
         
  +  
CH3–CH=CH2
  +  
2
KBr
  +  
H2O

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  +  
H2O

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© Mark R. Leach 1999 –


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