Interactions | Reactions | Processes

Classified as: Decomplexation or Fragmentation

Decomplexation or fragmentation is the reverse of complexation. However, where complexation is a bimolecular (second order) process, decomplexation is a unimolecular (first order) process.

Fragmentation into a Lewis acid/base pair is termed "heterolysis" and fragmentation into a pair of radicals is termed "homolysis".

For more information look in the Chemogenesis webbook sections on fragmentation reactions.
  +  
Pt
         
  +  
H2

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  +  
Pt
         
  +  
3
H2

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[H2O2]+•
         
HO•
  +  
[OH]–

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R–C–R
  +  
  +  

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  +  
  +  

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  +  
  +  

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  +  
  +  

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(CH3)3CBr
         
  +  
HBr

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  +  
(CH3)3N
         
  +  
[CN]–
  +  
[(CH3)3NH]+

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H2C=CH2
  +  
RCOOH

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  +  
[OH]–
         
  +  
(CH3)3N
  +  
H2O

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(CH3)3C–NH2
  +  
HNO2
         
  +  
N2
  +  
H2O
  +  
[OH]–

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R–NH2
  +  
HNO2
         
R+
  +  
N2
  +  
H2O
  +  
[OH]–

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CH2N2
         
N2
  +  
CH2

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  +  
HNO2
         
RCOOH
  +  
N2

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  +  
CO2
  +  
CO

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  +  
N2
  +  
CO2

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2
H2NCl
  +  
H2N–NH2
         
N2
  +  
2
NH4Cl

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3
H2NCl
  +  
2
NH3
         
N2
  +  
3
NH4Cl

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4
H2N–OH
  +  
H+
         
N2O
  +  
2
NH3
  +  
3
H2O

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N2O3
  +  
2
H2SO4
         
2
[NO]+
  +  
2
[HSO4]–
  +  
H2O

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2
HNO2
         
NO2
  +  
NO
  +  
H2O

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H2C=C=O
  +  
hν
         
CH2
  +  
CO

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RCOO–
         
R–
  +  
CO2

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R2C=C=O
  +  
hν
         
R–C–R
  +  
CO

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2
R–C–R

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  +  
H2O
  +  
HCl(aq)
         
  +  
CO2
  +  
CH3CH2OH

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  +  
[SCN]–
         
  +  
[NCO]–
  +  
CO2

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2
H2C=C=O
         

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NO2
  +  
hν
         
NO
  +  
O

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H2O
  +  
hν
         
H•
  +  
HO•

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H2O
  +  
hν
         
H2
  +  
O

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HOOH
  +  
hν
         
2
HO•

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CO2
  +  
hν
         
CO
  +  
O

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H2C=CH2
  +  
hν
         
HC≡CH
  +  
H2

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  +  
hν
         
H2C=CH2
  +  

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RCHO
  +  
hν
         
R–H
  +  
CO

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  +  
hν
         
2
H2C=CH2
  +  
CO

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  +  
hν
         
  +  
CO

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O3
  +  
hν
         
O
  +  
O2

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O3
  +  
O
         
2
O2

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  +  
Pt
         
  +  
4
H2

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2
H2O
         
2
H2
  +  
O2

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S2F10
         
SF6
  +  
SF4

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SO2
  +  
H2O
         
H2SO3

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[Cr2O7]2–
  +  
2
NaOH(aq)
         
2
[CrO4]2–
  +  
2
Na+
  +  
H2O

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[CH3CH2]+
  +  
H2O

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[CH3CH2]+
         
H2C=CH2
  +  
H+

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[NO2]+
  +  
H2O

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  +  
H+

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  +  
LiCH3
         
H2C=CH2
  +  
  +  
Li+
  +  
CH4

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3
  +  
3
O2

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CH3COONa
  +  
NaOH
         
CH4
  +  
Na2CO3

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© Mark R. Leach 1999 –

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