Interactions | Reactions | Processes


Classified as: Radical Cleavage

Radical cleavage (also called radical fragmentation or homolytic fission) occurs when a chemical bond undergoes homolytic fission to yield a pair of radicals.

For more information look in the Chemogenesis webbook sections on fragmentation reactions and dealing with radical chemistry.


(C6H5COO)2
  +  
hν
         
  +  

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Cl2
  +  
hν
         
2
Cl•

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Br2
  +  
hν
         
Br•
  +  
Br•

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  +  
CH3

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CH3
  +  
CO

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  +  
hν
         
  +  
CH3CH2

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  +  
hν
         
  +  
(CH3)3C•

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[H2O2]+•
         
HO•
  +  
[OH]

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(CH3CO)2CO
         
H2C=C=O
  +  
CH3COOH

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  +  
hν
         
  +  
CH3

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2
H•
         
H2

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  +  
m
         
CO
  +  
H•
  +  
m*

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CH4
  +  
m*
         
CH3
  +  
H•
  +  
m

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  +  
O2
         
CO
  +  
HO•

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  +  
3
O2
  +  
CH3COOH
         
  +  
2
H2O

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  +  

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  +  
CH3–CH=CH2

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  +  
3
H2C=CH2
  +  
2
CH3–CH=CH2

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© Mark R. Leach 1999 –


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