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Interactions | Reactions | Processes
Classified as: Radical Cleavage
Radical cleavage (also called radical fragmentation or homolytic fission) occurs when a chemical bond undergoes homolytic fission to yield a pair of radicals.
For more information look in the Chemogenesis webbook sections on fragmentation reactions and dealing with radical chemistry.![](http://www.chemthes.com/mech/28.gif)
(C6H5COO)2 |
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hν |
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Cl2 |
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hν |
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2 |
Cl• |
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Br2 |
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hν |
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Br• |
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Br• |
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CH3• |
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CH3• |
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CO |
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hν |
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CH3CH2• |
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hν |
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(CH3)3C• |
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[H2O2]+• |
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HO• |
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[OH]– |
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(CH3CO)2CO |
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H2C=C=O |
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CH3COOH |
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hν |
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CH3• |
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2 |
H• |
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H2 |
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m |
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CO |
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H• |
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m* |
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CH4 |
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m* |
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CH3• |
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H• |
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m |
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O2 |
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CO |
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HO• |
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3 |
O2 |
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CH3COOH |
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2 |
H2O |
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CH3–CH=CH2 |
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3 |
H2C=CH2 |
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2 |
CH3–CH=CH2 |
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© Mark R. Leach 1999 –
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