Interactions | Reactions | Processes


Classified as: Cracking, Thermal

Thermal cracking involves breaking longer alkanes into a mixture of shorter alkanes (including branched alkanes) and the olefins: ethene and propene.

The mechanism involves radical cleavage and then radical beta-eliminateion of ethene or propene, the reverse of radical polymerisation.


6
CH4
  +  
O2
         
2
HC≡CH
  +  
2
CO
  +  
10
H2

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CH3CH3
         
H2C=CH2
  +  
H2

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  +  

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  +  
H2C=CH2

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  +  
         
  +  

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  +  
CH3–CH=CH2

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Naphtha
         
Gasoline
  +  
H2C=CH2
  +  
CH3–CH=CH2

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Gas Oil
         
Gasoline
  +  
H2C=CH2
  +  
CH3–CH=CH2

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Naphtha
  +  
Gas Oil
         
  +  
  +  
  +  

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Naphtha
  +  
Gas Oil
         
  +  
  +  

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Naphtha
  +  
Gas Oil
         
  +  

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Gas Oil
  +  
Fuel oil
         

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CH4
  +  
Natural
Gas
  +  
Naphtha
  +  
Crude Oil
         
HC≡CH
  +  
H2C=CH2

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  +  
3
H2C=CH2
  +  
2
CH3–CH=CH2

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  +  
H2C=CH2

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  +  
  +  
[CH3CH2]+
  +  
[CH3]+

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© Mark R. Leach 1999 –


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