Interactions | Reactions | Processes

Classified as: Ease of Reduction of Organic FGs by Hydrogenation

Many organic functional groups are reduced under catalytic hydrogenation conditions, although some are reduced more easily than others.

After H.O. House.

For more information look in the Chemogenesis webbook section on redox chemistry.
RCOCl
  +  
H2
  +  
Pd
on BaSO4
         
RCHO
  +  
HCl

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R–C≡C–R
  +  
H2
  +  
Pd + Pb
on CaCO3
Lindlar Cat.
         

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RCHO
  +  
H2
  +  
Ru
on carbon
  +  
H2O
         
RCH2OH

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  +  
3
H2
  +  
Rh
on Carbon
         

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  +  
H2
  +  
Ru
on carbon
  +  
H2O
         
R2CHOH

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R–CN
  +  
2
H2
  +  
Pd
on C
         
RCH2NH2

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  +  
2
H2
  +  
Pd
on C
         

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  +  
H2
  +  
Pd
on C
         

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R–NO2
  +  
3
H2
  +  
Pd
on C
         
R–NH2
  +  
2
H2O

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  +  
H2
  +  
Pd
on C
         
  +  
R–OH

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  +  
2
H2
  +  
Pd
on C
         
RCH2OH
  +  
R–OH

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  +  
2
H2
  +  
Pd
on C
         
  +  
H2O

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RCOO–
  +  
H2
  +  
Pd
on C
         
RCOO–

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© Mark R. Leach 1999 –

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please contact Mark R. Leach, the author, using mark@meta-synthesis.com