Interactions | Reactions | Processes

Classified as: Substitution: Nucleophilic First Order

First order nucleophilic substitution occurs when a nucleofugal Lewis base leaving group spontaneously leaves a carbon centre (often with solvent assistance) to form a planar carbenium ion which subsequently attacked and complexed by a nucleophilic Lewis base.

For more information look in the Chemogenesis webbook sections on substitution reactions and substitution, transfer, abstraction, displacement (STAD).
(CH3)3COH
  +  
HCl(conc)
         
  +  
H2O

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(CH3)3COH
  +  
HBr
         
(CH3)3CBr
  +  
H2O

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(CH3)3COH
  +  
HI
         
(CH3)3CI
  +  
H2O

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  +  
[OH]–
         
  +  
  +  
Br–

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  +  
CH3COOH
         
  +  
  +  
HCl

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  +  
[NO2]–
         

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© Mark R. Leach 1999 –

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