Interactions | Reactions | Processes

Classified as: Substitution: Electrophilic Second Order

Second order electrophilic substitution involves a Lewis base transferring from one Lewis acid (Efg) to another (E).
RCl
  +  
AlCl3
         
R+ [AlCl4]–

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RCOCl
  +  
AlCl3
         

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  +  
Br2
  +  
CH3COOH
         
  +  
HBr

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  +  
CO
  +  
HCl
  +  
AlCl3
         
  +  
[AlCl4]–
  +  
H+

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  +  
Br2
         
  +  
LiBr

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  +  
ClCOOCH3
         
  +  
LiCl

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H3BO3
  +  
H2O
         
[B(OH)4]–
  +  
H+

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Al(OH)3
  +  
H2O
         
[Al(OH)4]–
  +  
H+

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RCOCl
  +  
AlCl3
         
[RCO]+
  +  
[AlCl4]–

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  +  
AlCl3
         
  +  
[AlCl4]–

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SbF5
  +  
HSO3F
         
ROH
  +  
SO3

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BF3
  +  
ClF3
         
[ClF2]+
  +  
[BF4]–

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SbF5
  +  
ClF3
         
[ClF2]+
  +  
[SbF6]–

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BrF5
  +  
CsF
         
Cs+
  +  
[BrF6]–

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IF5
  +  
KF
         
K+
  +  
[IF6]–

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IF7
  +  
CsF
         
Cs+
  +  
[IF8]–

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I–Cl
  +  
KCl
         
K+
  +  
[ICl2]–

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I–Cl
  +  
KI
         
K+
  +  
[I2Cl]–

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XeF2
  +  
HF
         
[XeF]+
  +  
[FHF]–

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XeF2
  +  
AsF5
         
[XeF]+
  +  
[AsF6]–

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XeF2
  +  
PF5
         
[XeF]+
  +  
[PF6]–

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XeF2
  +  
SbF5
         
[XeF]+
  +  
[SbF6]–

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RbF
  +  
XeF6
         
Rb+
  +  
[XeF7]–

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CsF
  +  
XeF6
         
Cs+
  +  
[XeF7]–

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ZrC
  +  
3
Pt
         
ZrPt3
  +  
C

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  +  
H2C=CH2
  +  
HCl
  +  
AlCl3
         

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  +  
  +  
HCl
  +  
AlCl3
         

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  +  
AlCl3
         
  +  
[AlCl4]–

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  +  
  +  
AlCl3
  +  
HCl
         

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© Mark R. Leach 1999 –

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please contact Mark R. Leach, the author, using mark@meta-synthesis.com