Interactions | Reactions | Processes


Classified as: Nitrous Acid with Amines and Amides

Nitrous acid, or HONO, shows markedly different reactivity with 1°, 2° and 3° amines.


  +  
HNO2
  +  
H+
  +  
H2O
         
  +  
2
H2O

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NaNO2
  +  
H+
         
HNO2
  +  
Na+

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R–NH2
  +  
HNO2
         
R+
  +  
N2
  +  
H2O
  +  
[OH]

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R2NH
  +  
HNO2
         
R2N–NO

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R3N
  +  
HNO2
         
R3N
  +  
HNO2

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© Mark R. Leach 1999 –


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