Interactions | Reactions | Processes

Classified as: Strategic Bond Formation

Strategic Bond Formation is a concept associated with "RetroSynthetic Analysis", RSA, a rational approach to the designing synthetic routes to large organic structures, usually of pharmaceutical interest. RSA considers organic reactions of synthetic utility to be of two general types: FGIs and Strategic Bond formation.
RCOCl
  +  
RMgX
  +  
         

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RCOCl
  +  
R2CuLi
  +  
         

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RCHO
  +  
RMgX
         
R2CHOH

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HCHO
  +  
RMgX
         
RCH2OH

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RCHO
  +  
         

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RCHO
  +  
RCH2CHO
  +  
OH–(aq)
         

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RCHO
  +  
         

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  +  
Zn(Cu)
  +  
CH2I2
         

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  +  
R+
         
  +  
H+

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  +  
RCl
  +  
AlCl3
         
  +  
[AlCl4]–

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  +  
[RCO]+
         

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  +  
RCOCl
  +  
AlCl3
         
  +  
H+
  +  
[AlCl4]–

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  +  
CuCN
         
  +  
N2
  +  
Cu+

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  +  
RMgX
         
R3COH

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  +  
  +  
R–OH
         
  +  
RO–

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2
  +  
CH3CH2O–
  +  
CH3CH2OH
         
  +  
CH3CH2O–

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  +  
HBr
         
R–OH
  +  
RBr

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RBr
  +  
         
R–Nu
  +  
Br–

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  +  
RMgX
         
R3COH

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  +  
         
  +  
(C6H5)3P=O

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R–CN
  +  
RMgX
         

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  +  
R2CuLi
         

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R2CuLi
  +  
RBr
         
R–R

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RMgX
  +  
CO2
         
RCOO–

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CH3•
  +  
CH3•
         
CH3CH3

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  +  
  +  
         

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  +  
  +  
         

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  +  
         
  +  

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  +  
         
  +  
RCOOH

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  +  
RMgBr
         
R–CH2CH2OH

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  +  
H2C=CH2
         

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CH2
  +  
H2C=CH2
         

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  +  
hν
         
  +  
CH3CH2•

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  +  
hν
         
  +  
(CH3)3C•

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CH2N2
  +  
H2C=CH2
         

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CH3–CH=CH2
  +  
H2C=CH2
         

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[RCO]+
  +  
R–
         

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[CH3CO]+
  +  
         

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© Mark R. Leach 1999 –

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