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Interactions | Reactions | Processes
Classified as: Type 23 Lewis Acid/Base Complexation Chemistry
Very many Type 23 "transition metal coordination" complexes are known.
For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.![](http://www.chemthes.com/mech/123.gif)
Pd |
+ |
4 |
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[(C6H5)3P]4Pd |
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Cr6+ |
+ |
3 |
O2– |
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CrO3 |
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Cu+ |
+ |
[CN]– |
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CuCN |
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Fe3+ |
+ |
3 |
Br– |
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FeBr3 |
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Fe3+ |
+ |
3 |
Cl– |
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FeCl3 |
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Pb4+ |
+ |
4 |
[CH3COO]– |
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Pb(OCOCH3)4 |
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Cu+ |
+ |
2 |
R– |
+ |
Li+ |
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R2CuLi |
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Hg2+ |
+ |
2 |
[CH3COO]– |
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Hg(OCOCH3)2 |
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Hg2+ |
+ |
O2– |
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HgO |
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Hg2+ |
+ |
[SO4]2– |
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HgSO4 |
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K+ |
+ |
[MnO4]– |
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KMnO4 |
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Sn2+ |
+ |
2 |
Cl– |
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SnCl2 |
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Zn2+ |
+ |
2 |
Br– |
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ZnBr2 |
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Bi3+ |
+ |
3 |
[NO3]– |
+ |
5 |
H2O |
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Bi(NO3)2 |
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Cd2+ |
+ |
2 |
Br– |
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CdBr2 |
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2 |
Ce3+ |
+ |
3 |
O2– |
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Ce2O3 |
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Ce4+ |
+ |
2 |
O2– |
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CeO2 |
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Cr2+ |
+ |
2 |
Cl– |
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CrCl2 |
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Cr3+ |
+ |
3 |
Cl– |
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CrCl3 |
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Co2+ |
+ |
[SO4]2– |
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CoSO4 |
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Cu2+ |
+ |
O2– |
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CuO |
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Fe2+ |
+ |
[CO3]2– |
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FeCO3 |
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Fe2+ |
+ |
[C2O4]2– |
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FeC2O4 |
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Pb2+ |
+ |
2 |
[CH3COO]– |
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Pb(CH3COO)2 |
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Ni2+ |
+ |
[CO3]2– |
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NiCO3 |
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Ni |
+ |
4 |
CO |
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Ni(CO)4 |
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Zr4+ |
+ |
4 |
Cl– |
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ZrCl4 |
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Ag+ |
+ |
Cl– |
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AgCl |
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Ag+ |
+ |
Br– |
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AgBr |
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Ag+ |
+ |
[BrO3]– |
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AgBrO3 |
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Ag+ |
+ |
[SCN]– |
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AgSCN |
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2 |
Ag+ |
+ |
[C2O4]2– |
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AgC2O4 |
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2 |
Ag+ |
+ |
[CrO4]2– |
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Ag2CrO4 |
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Ag+ |
+ |
I– |
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AgI |
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Ag+ |
+ |
[IO3]– |
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AgIO3 |
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3 |
Ag+ |
+ |
[PO4]3– |
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Ag3PO4 |
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2 |
Ag+ |
+ |
S2– |
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Ag2S |
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2 |
Ag+ |
+ |
[SO4]2– |
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Ag2SO4 |
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2 |
Bi3+ |
+ |
3 |
S2– |
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Ba2S3 |
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Cd2+ |
+ |
S2– |
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CdS |
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Co2+ |
+ |
2 |
[OH]– |
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Co(OH)2 |
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Co3+ |
+ |
3 |
[OH]– |
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Co(OH)3 |
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Co2+ |
+ |
S2– |
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CoS |
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Cu+ |
+ |
Br– |
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CuBr |
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Cu+ |
+ |
Cl– |
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CuCl |
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Cu+ |
+ |
I– |
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CuI |
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Cu2+ |
+ |
S2– |
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2 |
Cu+ |
+ |
S2– |
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Cu2S |
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Cu+ |
+ |
[SCN]– |
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CuSCN |
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Fe2+ |
+ |
2 |
[OH]– |
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Fe(OH)2 |
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Fe3+ |
+ |
3 |
[OH]– |
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Fe(OH)3 |
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Fe2+ |
+ |
S2– |
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FeS |
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Hg23+ |
+ |
2 |
Br– |
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Hg2Br2 |
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Hg23+ |
+ |
2 |
Cl– |
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Hg2Cl2 |
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Hg23+ |
+ |
2 |
I– |
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Hg2I2 |
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Hg23+ |
+ |
S2– |
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Hg2S |
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Hg2+ |
+ |
S2– |
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HgS |
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Mg2+ |
+ |
2 |
[OH]– |
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Mn(OH)2 |
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Mg2+ |
+ |
S2– |
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MnS |
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Ni2+ |
+ |
2 |
[OH]– |
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Ni(OH)2 |
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Ni2+ |
+ |
S2– |
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Pb2+ |
+ |
2 |
Br– |
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PbBr2 |
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Pb2+ |
+ |
2 |
Cl– |
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PbCl2 |
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Pb2+ |
+ |
[CO3]2– |
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PbCO3 |
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Pb2+ |
+ |
[CrO4]2– |
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PbCrO4 |
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Pb2+ |
+ |
2 |
F– |
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PbF2 |
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Pb2+ |
+ |
2 |
I– |
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PbI2 |
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3 |
Pb2+ |
+ |
2 |
[PO4]3– |
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Pb3(PO4)2 |
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Pb2+ |
+ |
S2– |
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PbS |
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Pb2+ |
+ |
[SO4]2– |
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PbSO4 |
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Tl+ |
+ |
Cl– |
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TlCl |
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Tl+ |
+ |
I– |
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TlI |
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2 |
Tl+ |
+ |
S2– |
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Tl2S |
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Zn2+ |
+ |
2 |
[OH]– |
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Zn(OH)2 |
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Zn2+ |
+ |
S2– |
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ZnS |
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Cu2+ |
+ |
2 |
[OH]– |
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Cu(OH)2 |
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Cu2+ |
+ |
2 |
[NO3]– |
+ |
6 |
H2O |
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Cu(NO3)2 |
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Pb2+ |
+ |
2 |
[NO3]– |
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Pb(NO3)2 |
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Ag+ |
+ |
[NO3]– |
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AgNO3 |
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Hg2+ |
+ |
2 |
Cl– |
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HgCl2 |
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Sn2+ |
+ |
O2– |
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SnO |
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Cu2+ |
+ |
[SO4]2– |
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CuSO4 |
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Zr4+ |
+ |
[SiO4]4– |
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ZrSiO4 |
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2 |
Zn2+ |
+ |
[SiO4]4– |
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Zn2SiO4 |
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Y3+ |
+ |
[PO4]3– |
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YPO4 |
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Pb2+ |
+ |
2 |
[MnO4]– |
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Pb(MnO4)2 |
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Mg2+ |
+ |
[WO4]2– |
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MnWO4 |
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Fe2+ |
+ |
[WO4]2– |
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FeWO4 |
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Zn2+ |
+ |
[CO3]2– |
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ZnCO3 |
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Mg2+ |
+ |
[CO3]2– |
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MnCO3 |
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U4+ |
+ |
2 |
O2– |
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UO2 |
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Ti4+ |
+ |
2 |
O2– |
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TiO2 |
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Sn4+ |
+ |
2 |
O2– |
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Sn2O |
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Fe2+ |
+ |
O2– |
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FeO |
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2 |
Fe3+ |
+ |
3 |
O2– |
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Fe2O3 |
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Fe2+ |
+ |
2 |
Fe3+ |
+ |
4 |
O2– |
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FeO.Fe2O3 |
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Zn2+ |
+ |
O2– |
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ZnO |
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W6+ |
+ |
3 |
O2– |
+ |
H2O |
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WO3.H2O |
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2 |
Cu+ |
+ |
O2– |
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Cu2O |
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Mo4+ |
+ |
2 |
S2– |
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MoS2 |
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2 |
Sb3+ |
+ |
3 |
S2– |
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Sb2S3 |
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2 |
As3+ |
+ |
3 |
S2– |
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As2S3 |
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+ |
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Pt2+ |
+ |
H– |
+ |
2 |
(CH3CH2)3P |
+ |
Cl– |
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Pd2+ |
+ |
2 |
Cl– |
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PdCl2 |
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Fe |
+ |
5 |
CO |
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Fe(CO)5 |
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4 |
Ag |
+ |
8 |
NaCN |
+ |
O2 |
+ |
2 |
H2O |
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4 |
Na[Ag(CN)2] |
+ |
4 |
NaOH |
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4 |
Au |
+ |
8 |
NaCN |
+ |
O2 |
+ |
2 |
H2O |
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4 |
Na[Au(CN)2] |
+ |
4 |
NaOH |
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Ag+ |
+ |
2 |
[CN]– |
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[Ag(CN)2]– |
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Au+ |
+ |
2 |
[CN]– |
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[Au(CN)2]– |
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Zn2+ |
+ |
2 |
Cl– |
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ZnCl2 |
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Pt2+ |
+ |
4 |
Cl– |
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[PtCl4]2– |
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Fe3O4 |
+ |
8 |
HCl |
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FeCl2 |
+ |
2 |
FeCl3 |
+ |
4 |
H2O |
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Zn2+ |
+ |
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ZnS2O3 |
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2 |
Co |
+ |
8 |
CO |
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Co2(CO)8 |
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Hg2+ |
+ |
2 |
[O=N=C]– |
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Hg(ONC)2 |
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Hg2+ |
+ |
2 |
[NO3]– |
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Hg(NO3)2 |
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Pb2+ |
+ |
2 |
[N3]– |
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Pb(N3)2 |
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Cu2+ |
+ |
4 |
Cl– |
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[CuCl4]2– |
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Cu2+ |
+ |
6 |
H2O |
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[Cu(H2O)6]2+ |
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CuSO4 |
+ |
6 |
H2O |
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[Cu(H2O)6]2+ |
+ |
[SO4]2– |
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Cu2+ |
+ |
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[Cu(EDTA)]2– |
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[Cu(H2O)6]2+ |
+ |
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[Cu(EDTA)]2– |
+ |
6 |
H2O |
![]() |
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+ |
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+ |
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+ |
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Fe2+ |
+ |
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+ |
2 |
H+ |
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Ag+ |
+ |
2 |
NH3 |
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[Ag(NH3)2]+ |
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Ag+ |
+ |
2 |
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[Ag(S2O3)2]3– |
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Ag+ |
+ |
2 |
[CN]– |
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[Ag(CN)2]– |
![]() |
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Fe2+ |
+ |
6 |
H2O |
![]() |
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[Fe(H2O)6]2+ |
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Fe3+ |
+ |
6 |
H2O |
![]() |
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[Fe(H2O)6]3+ |
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Cr2+ |
+ |
6 |
H2O |
![]() |
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[Cr(H2O)6]2+ |
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Cr3+ |
+ |
6 |
H2O |
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[Cr(H2O)6]2+ |
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[Cr(H2O)6]2+ |
+ |
6 |
NH3(aq) |
![]() |
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[Cr(NH3)6]2+ |
+ |
6 |
H2O |
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Co2+ |
+ |
6 |
H2O |
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[Co(H2O)6]2+ |
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[Cu(H2O)6]2+ |
+ |
4 |
NH3(aq) |
![]() |
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[Cu(NH3)4(H2O)2]2+ |
+ |
4 |
H2O |
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Co2+ |
+ |
4 |
Cl– |
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[CoCl4]2– |
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Cu2+ |
+ |
4 |
Cl– |
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[CuCl4]2– |
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[Cu(H2O)6]2+ |
+ |
4 |
Cl– |
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[CuCl4]2– |
+ |
6 |
H2O |
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[Co(H2O)6]2+ |
+ |
4 |
Cl– |
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[CoCl4]2– |
+ |
6 |
H2O |
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Fe2+ |
+ |
3 |
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[Fe(H2O)6]2+ |
+ |
3 |
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+ |
6 |
H2O |
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+ |
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+ |
6 |
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+ |
3 |
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+ |
6 |
![]() |
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Ni2+ |
+ |
3 |
![]() |
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[Ni(en)3]2+ |
![]() |
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[Fe(H2O)6]3+ |
+ |
3 |
[C2O4]2– |
![]() |
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[Fe(C2O4)3]3– |
+ |
6 |
H2O |
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Fe3+ |
+ |
3 |
[C2O4]2– |
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[Fe(C2O4)3]3– |
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[Fe(H2O)6]3+ |
+ |
[SCN]– |
![]() |
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[Fe(H2O)5(SCN)]2+ |
+ |
H2O |
![]() |
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V3+ |
+ |
4 |
H2O |
+ |
2 |
Cl– |
![]() |
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[VCl2(H2O)4]+ |
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V2+ |
+ |
6 |
H2O |
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[V(H2O)6]2+ |
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Mg2+ |
+ |
6 |
H2O |
![]() |
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[Mn(H2O)6]2+ |
![]() |
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AgBr |
+ |
2 |
![]() |
+ |
hν |
![]() |
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![]() |
[Ag(S2O3)2]3– |
+ |
Br– |
![]() |
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![]() |
[Fe(H2O)6]2+ |
+ |
[SO4]2– |
+ |
H2O |
![]() |
![]() |
![]() |
FeSO4.7H2O |
![]() |
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[Co(H2O)6]2+ |
+ |
2 |
Cl– |
![]() |
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CoCl2.6H2O |
![]() |
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[Fe(H2O)6]3+ |
+ |
3 |
[NO3]– |
+ |
3 |
H2O |
![]() |
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Fe(NO3)3 .9H2O |
![]() |
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[Al(H2O)6]3+ |
+ |
3 |
Cl– |
![]() |
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AlCl3.6H2O |
![]() |
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Fe2(SO4)3 .5H2O |
+ |
7 |
H2O |
![]() |
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2 |
[Fe(H2O)6]3+ |
+ |
3 |
[SO4]2– |
![]() |
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[Co(H2O)6]2+ |
+ |
4 |
HCl(conc) |
![]() |
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[CoCl4]2– |
+ |
4 |
H+ |
+ |
6 |
H2O |
![]() |
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AgCl |
+ |
2 |
NH3(aq) |
![]() |
![]() |
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[Ag(NH3)2]+ |
+ |
Cl– |
![]() |
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[Ag(NH3)2]+ |
+ |
NaBr |
+ |
H2O |
![]() |
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![]() |
AgBr |
+ |
2 |
NH3 |
+ |
Na+ |
![]() |
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![]() |
AgBr |
+ |
2 |
Na2S2O3 |
+ |
H2O |
![]() |
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[Ag(S2O3)2]3– |
+ |
4 |
Na+ |
+ |
Br– |
![]() |
![]() |
![]() |
AgBr |
+ |
2 |
KCN |
+ |
H2O |
![]() |
![]() |
![]() |
[Ag(CN)2]– |
+ |
2 |
K+ |
+ |
Br– |
![]() |
![]() |
![]() |
[Ag(CN)2]– |
+ |
e– |
+ |
K+ |
+ |
H2O |
![]() |
![]() |
Ag |
+ |
2 |
[CN]– |
+ |
K+ |
![]() |
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Co2+ |
+ |
3 |
![]() |
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![]() |
[Co(en)3]2+ |
![]() |
![]() |
![]() |
![]() |
![]() |
[Co(H2O)6]2+ |
+ |
![]() |
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![]() |
![]() |
![]() |
[Co(EDTA)]3– |
+ |
6 |
H2O |
![]() |
![]() |
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Co2+ |
+ |
![]() |
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![]() |
[Co(EDTA)]3– |
![]() |
![]() |
![]() |
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![]() |
CuCl2 |
+ |
2 |
HCl(conc) |
![]() |
![]() |
![]() |
![]() |
[CuCl4]2– |
+ |
2 |
H+ |
![]() |
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Cu+ |
+ |
4 |
Cl– |
![]() |
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[CuCl4]3– |
![]() |
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Ag+ |
+ |
2 |
Cl– |
![]() |
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[AgCl2]– |
![]() |
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![]() |
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AgBr |
+ |
2 |
.880 NH3 |
![]() |
![]() |
![]() |
![]() |
[Ag(NH3)2]+ |
+ |
Br– |
![]() |
![]() |
![]() |
![]() |
Ag+ |
+ |
[NO3]– |
+ |
Na+ |
+ |
Cl– |
+ |
H2O |
![]() |
AgCl |
+ |
Na+ |
+ |
[NO3]– |
![]() |
![]() |
![]() |
Ag+ |
+ |
[NO3]– |
+ |
Na+ |
+ |
Br– |
+ |
H2O |
![]() |
AgBr |
+ |
Na+ |
+ |
[NO3]– |
![]() |
![]() |
![]() |
Ag+ |
+ |
[NO3]– |
+ |
Na+ |
+ |
I– |
+ |
H2O |
![]() |
AgI |
+ |
Na+ |
+ |
[NO3]– |
![]() |
![]() |
![]() |
2 |
AgNO3 |
+ |
Na2CO3 |
+ |
H2O |
![]() |
![]() |
![]() |
Ag2CO3 |
+ |
2 |
NaNO3 |
![]() |
![]() |
![]() |
![]() |
2 |
Ag+ |
+ |
2 |
[NO3]– |
+ |
2 |
Na+ |
+ |
[CO3]2– |
+ |
H2O |
![]() |
Ag2CO3 |
+ |
2 |
Na+ |
+ |
2 |
[NO3]– |
![]() |
![]() |
![]() |
2 |
Ag+ |
+ |
[CO3]2– |
![]() |
![]() |
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![]() |
Ag2CO3 |
![]() |
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Ag+ |
+ |
[NO3]– |
+ |
K+ |
+ |
Br– |
+ |
H2O |
![]() |
AgBr |
+ |
K+ |
+ |
[NO3]– |
![]() |
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Ag+ |
+ |
Br– |
+ |
H2O |
![]() |
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AgBr |
![]() |
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Ag+ |
+ |
Cl– |
+ |
H2O |
![]() |
![]() |
![]() |
AgCl |
![]() |
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![]() |
![]() |
![]() |
AgBr |
+ |
2 |
[CN]– |
+ |
H2O |
![]() |
![]() |
![]() |
[Ag(CN)2]– |
+ |
Br– |
![]() |
![]() |
![]() |
![]() |
Ag+ |
+ |
2 |
[CN]– |
![]() |
![]() |
![]() |
![]() |
[Ag(CN)2]– |
![]() |
![]() |
![]() |
![]() |
![]() |
CaBr2 |
+ |
2 |
AgNO3 |
+ |
H2O |
![]() |
![]() |
![]() |
2 |
AgBr |
+ |
Ca2+ |
+ |
2 |
[NO3]– |
![]() |
![]() |
![]() |
[VO]2+ |
+ |
5 |
H2O |
![]() |
![]() |
![]() |
![]() |
[VO]2+ |
![]() |
![]() |
![]() |
![]() |
![]() |
BaCl2 |
+ |
2 |
AgNO3 |
+ |
H2O |
![]() |
![]() |
![]() |
2 |
AgCl |
+ |
Ba2+ |
+ |
2 |
[NO3]– |
![]() |
![]() |
![]() |
2 |
Cu2+ |
+ |
4 |
I– |
+ |
H2O |
![]() |
![]() |
![]() |
2 |
CuI |
+ |
I2 |
![]() |
![]() |
![]() |
![]() |
[CrO4]2– |
+ |
2 |
AgNO3 |
+ |
H2O |
![]() |
![]() |
![]() |
Ag2CrO4 |
+ |
2 |
[NO3]– |
![]() |
![]() |
![]() |
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© Mark R. Leach 1999 –
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