Interactions | Reactions | Processes

Classified as: Type 14 Lewis Acid/Base Complexation Chemistry

Type 14 complexes are often generated as reactive intermediates with the Complex anion Lewis base acting as a non-nucleophilic counter ion to reactive electrophilic Lobe-LUMO Lewis acid.

Friedel-Crafts reactions, for example, employ Type 14 Lewis acid/base complexes.

For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.

Cl+
  +  
[AlCl4]–
         
Cl+ / [AlCl4]–

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[NO2]+
  +  
[BF4]–
         
[NO2]+[BF4]–

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Br+
  +  
[FeBr4]–
         
Br+ [FeBr4]–

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R+
  +  
[AlCl4]–
         
R+ [AlCl4]–

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[RCO]+
  +  
[AlCl4]–
         

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  +  
         

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[N5]+
  +  
[AsF6]–
         
[N5]+ [AsF6]–

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Cl+
  +  
[ClO4]–
         
Cl+ [ClO4]–

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[XeF]+
  +  
[PtF6]–
         
[XeF]+
[PtF6]–

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© Mark R. Leach 1999 –

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