Interactions | Reactions | Processes

Classified as: Type 13 Lewis Acid/Base Complexation Chemistry

Many C-H bonds, which are usually polarised as Type 3 complexes (ie delta+ H), are often formed via Type 13 interactions in which a hydride ion reduces a Lobe-LUMO Lewis acid.

For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.

HCHO
  +  
H–
         
[CH3–O]–

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RCHO
  +  
H–
         
R–CH2O–

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CH3CHO
  +  
H–
         
CH3CH2O–

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  +  
H–
         
[(CH3)2CH–O]–

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[RCO]+
  +  
H–
         
RCHO

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[CH3CO]+
  +  
H–
         
CH3CHO

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Al3+
  +  
3
H–
         

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Br+
  +  
H–
         
HBr

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Cl+
  +  
H–
         
HCl

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I+
  +  
H–
         
HI

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[RCH2CH2]+
  +  
H–
         
R–CH3

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[R2CH]+
  +  
H–
         

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AlH3
  +  
H–
         
[AlH4]–

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  +  
         

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InH3
  +  
H–
         
[InH4]–

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GaH3
  +  
H–
         
[GaH4]–

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BH3
  +  
H–
         
[BH4]–

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[CH3]+
  +  
H2
         
[CH5]+

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© Mark R. Leach 1999 –

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please contact Mark R. Leach, the author, using mark@meta-synthesis.com