Interactions | Reactions | Processes

Classified as: Type 11 Lewis Acid/Base Complexation Chemistry

Generally Onium ion Lewis acids do not complex with Lobe-HOMO Lewis bases, because the Onium ion is liable to transfer a ligand to the Lobe-HOMO Lewis base.

NH4OH (ammonium hydroxide) is clearly a Type 11 Lewis acid/base complex. This species exists in an equilibrium state with NH3 + H2O.

For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.

  +  
HBF4(aq)
  +  
H2O
  +  
         
  +  
[BF4]–

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[H3O]+
  +  
         

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  +  
Cl–
         

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[NH4]+
  +  
[CH3COO]–
         
[NH4]+[CH3CO2]–

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[NH4]+
  +  
Cl–
         
NH4Cl

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[NH4]+
  +  
[NO3]–
         
NH4NO3

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2
[NH4]+
  +  
S2–
         
(NH4)2S

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[NH4]+
  +  
[HS]–
         
NH4HS

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  +  
I–
         

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  +  
         

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  +  
         
  +  

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[NH4]+
  +  
[FHF]–
         
[NH4]+ [FHF]–

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NH3
  +  
HCl
         
NH4Cl

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[NH4]+
  +  
[ClO4]–
         
NH4ClO4

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2
[NH4]+
  +  
         
(NH4)2S2O8

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2
[NH4]+
  +  
[SO3]2–
  +  
H2O
         
(NH4)2SO3
.H2O

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2
[NH4]+
  +  
         
(NH4)2S2O3

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[NH4]+
  +  
F–
         
NH4F

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[NH4]+
  +  
[VO3]–
         
NH4VO3

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[H3O]+
  +  
[OH]–
         
2
H2O

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© Mark R. Leach 1999 –

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please contact Mark R. Leach, the author, using mark@meta-synthesis.com