Interactions | Reactions | Processes

Classified as: Type 6 Lewis Acid/Base Complexation Chemistry

Type 6 complexes form when s-LUMO Lewis acids interact with Complex Anion Lewis bases to form the classic charge controlled (ionic) species such as lithium tetrafluoroborate, Li[BF4].

Type 6 complexes tend to be highly soluble in polar solvents in which the anion and cation are independently solvated: solvated Type 6 complexes show little or no ion-pairing.

For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.

Na+
  +  
[BF4]–
         
NaBF4

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Li+
  +  
[AlH4]–
         
LiAlH4

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Na+
  +  
[BH4]–
         
NaBH4

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2
K+
  +  
[PtCl6]2–
         
K2[PtCl6]

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3
Na+
  +  
[AlF6]3–
         
Na3AlF6

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2
Na+
  +  
[Cr2O7]2–
         
Na2Cr2O7
.H2O

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  +  
         

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2
K+
  +  
[ReH9]2–
         
K2ReH9

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2
Na+
  +  
[SiF6]2–
         
Na2[SiF6]

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C60
  +  
3
K
         
K3C60

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4
Ag
  +  
8
NaCN
  +  
O2
  +  
2
H2O
         
4
Na[Ag(CN)2]
  +  
4
NaOH

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4
Au
  +  
8
NaCN
  +  
O2
  +  
2
H2O
         
4
Na[Au(CN)2]
  +  
4
NaOH

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Na+
  +  
[Ag(CN)2]–
         
Na[Ag(CN)2]

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Na+
  +  
[Au(CN)2]–
         
Na[Au(CN)2]

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K+
  +  
[ClO4]–
         
KClO4

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Na+
  +  
[ClO4]–
         
NaClO4

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K+
  +  
[BrO4]–
         
NaBrO4

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BrF5
  +  
CsF
         
Cs+
  +  
[BrF6]–

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IF5
  +  
KF
         
K+
  +  
[IF6]–

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IF7
  +  
CsF
         
Cs+
  +  
[IF8]–

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RbF
  +  
XeF6
         
Rb+
  +  
[XeF7]–

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CsF
  +  
XeF6
         
Cs+
  +  
[XeF7]–

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2
Rb+
  +  
2
[XeF7]–
         
2
Rb+
  +  
[XeF8]2–
  +  
XeF6

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2
Cs+
  +  
2
[XeF7]–
         
2
Cs+
  +  
[XeF8]2–
  +  
XeF6

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2
K+
  +  
[PtCl4]2–
         
K2[PtCl4]

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Na+
  +  
[CrO4]2–
         
Na2CrO4

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2
K+
  +  
[MnO4]2–
         
K2MnO4

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3
K+
  +  
[MnO4]3–
         
K3MnO4

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2
Mg2+
  +  
[FeH6]4–
         
Mg2FeH6

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2
Mg2+
  +  
[CoH5]4–
         
Mg2CoH5

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2
Mg2+
  +  
[NiH4]4–
         
Mg2NiH4

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2
K+
  +  
[ZnH4]2–
         
K2ZnH4

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© Mark R. Leach 1999 –

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