Interactions | Reactions | Processes


Classified as: Type 4 Lewis Acid/Base Complexation Chemistry

Type 4 complexes form when pi-System Lewis bases are protonated. Type 4 Lewis acid/base complexes may be very weak Brønsted acids (for example toluene, the H+/benzyl anion complex, pKa 42) or they may be strong acids like protonated ethylene (the methyl carbenium ion) pKa 15.

For more information look in the Chemogenesis webbook sections on Lewis acids and Lewis bases and the Lewis acid/base interaction matrix.


H+
  +  
         

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H+
  +  
         

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H+
  +  
         

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H+
  +  
         

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H+
  +  
         

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H+
  +  
         
CH3–CH=CH2

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H+
  +  
         

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H+
  +  
         

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H+
  +  
         
R+

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H+
  +  
         

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H+
  +  
         

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  +  
         

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H+
  +  
         

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H+
  +  
[IO4]
         
HIO4

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H2C=CH2
  +  
HBr
  +  
AlBr3
         
CH3CH2Br

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  +  
H+

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CH3–CH=CH2
  +  
H+
         

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[CH3CH2]+
         
H2C=CH2
  +  
H+

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  +  
H+

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© Mark R. Leach 1999 –


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